It should not be confused with the term stress corrosion cracking which is an anodic cracking mechanism. Sulfide stress cracking ssc vs hydrogen induced cracking hlc posted in refining, hydrocarbons, oil, and gas. Producing wet sour gas presents some of the toughest technical challenges in the oil and gas business. Srbs produce hydrogen sulfide, which can cause accelerated corrosion and sulfide stress cracking ssc. Processes or conditions involving wet hydrogen sulfide, i. Standard test method laboratory testing of metals for. Electrochemical and sulfide stress corrosion cracking.
Wet h 2 s corrosion can be a particularly dangerous form of corrosion because damage caused by it takes place on the interior of. Sulfide stress corrosion cracking and hydrogen induced. This is an embrittlement caused by diffusion of metal atoms, either liquid or solid, into the metal. When sulfides are present in caustic solutions the scc has been reported to occur at lower temperatures. H2s and hydrogen attackcorrosion refining, hydrocarbons. Susceptibility to sohic for linepipepressure vessel steels twi. Sulfide stress cracking an overview sciencedirect topics. Ssc quickly diminishes performance of downhole tubulars. Pdf the wellhead flow control valve bodies which are the focal point of this failure case study were installed in some of the upstream facilities of. In other words, it can support a stress of 80,000 psi with an elongation of less than 0. Pdf sulfide stress corrosion cracking and hydrogen induced.
The susceptibility of a high strength low alloy nanostructured steel to sulfide stress corrosion cracking sscc resistance is assessed. The surface morphology analysis indicated that surface damage and uniform plastic deformation. Iso 151563 will set new restrictions on uns s174000 174ph october 22, 2014 by mariano. Sulfide stress cracking ssc testing southwest research institute. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process environments. The letter in conjunction with the number designates parameters such as the maximum yield strength and the minimum ultimate strength which for l80 pipe are 95,000 psi. The required tensile stresses may be in the form of directly applied stresses or in the form of residual.
Standard material requirements sulfide stress cracking. Pdf sulfide stress corrosion cracking and hydrogen. This article describes current industry practices to catalog features observed after sulfide stress cracking testing. Ricker, national institute of standards and technology stress corrosion cracking scc is a term used to describe service failures in engineering materials that occur by slow, environmentally induced crack propagation. In recognition of the variation with temperature and with different materials this phenomenon is here called environmental cracking ec. The article also introduces a quantitative criterion to determine the maximum allowable defect size based on fracture mechanics principles. Sulfide stress corrosion cracking and hydrogen induced cracking of a216wcc wellhead flow control valve body article pdf available in case studies in engineering failure analysis. The resistance to chlorideinduced stress corrosion cracking of uns n08031 was tested on ubend specimens according to astm g 30 for a testing time of 2000 hours. Sulfide stress corrosion cracking resistance was evaluated as per nace tm017796 method a using cylindrical test piece and a load ring. The ssc of medium strength steels has been a continuing source of trouble in the oil fields, and from these troubles has evolved in international standards 6. The applied stress was 70% and 100% of the yield strength ys of the material.
Hydrogen induced cracking and sulphide stress cracking of carbonmanganese steels 517 introduction, sulphide inclusions are considered as the most dangerous sites for hic initiation. This paper analyzed the hsla pipeline steels stress corrosion behavior and mechanism which tested in the saturated solution of h2s. Stress orientated hydrogen induced cracking sohic is a manifestation of sulfide stress cracking ssc in cmn steels by a mechanism involving the linking of planar cracks normal to the primary propagation direction of the crack. Although there are several kinds of cracking damage that can occur in metals, delayed brittle fracture of metals resulting from the combined action of corrosion in an aqueous sulfide environment and tensile stresses failure may occur at stresses far below the yield stress is the phenomenon known as ssc. Hydrogen sulfide stress corrosion cracking in materials. The reason for this is the complexity of the damage mechanism which is dependent on the particular material and damaging medium. The stress can be externally applied or it can be an internal residual stress.
Sulfide stress cracking nace mr01752002, mr0175iso 15156. Sulfide stress cracking ssc is one of the detrimental types of corrosion which happens in sour environment. Alloys which are commercially available and those which have modified metallurgical structures and. This standard addresses the testing of metals for resistance to cracking failure under the combined action of tensile stress and corrosion in aqueous environments containing hydrogen sulfide h 2 s.
Dec 19, 2019 sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. In the solution containing high pressure co2, cr, and p110 steels exhibited general. Webcorr provides corrosion consultancy services, corrosion expert witness and corrosion short courses for inhouse training, online and distance learning. Sulfide stress corrosion cracking, also known as sulfide stress cracking ssc, is a stress corrosion cracking phenomena that occurs in the presence of hydrogen sulfide. Corrosionpedia what is sulfide stress cracking ssc. Sulfide stress cracking is also called hydrogen sulfide cracking, sulfide cracking, sulfide corrosion cracking and. Subsequent improvements in the metallurgy of steels for highpressure gas and oil wells and improved selection methods for highstrength alloys have been based on laboratory test methods. Sulfide stress cracking, a form of hydrogen embrittlement, first became a serious problem in the oil industry in 1951. To our surprise, it was not true in the studied case. Hydrogen induced cracking and sulphide stress cracking of. Sulfide stress cracking ssc was first identified and the mechanism outlined in the 1940s after. Sulfide stress cracking how is sulfide stress cracking abbreviated. Stress orientated hydrogen induced cracking sohic is a manifestation of sulfide stress cracking ssc in cmn steels by a mechanism involving the linking of planar cracks normal to. Dissolved hydrogen can cause cracking, blistering, and embrittlement.
Sulfide stress cracking ssc occurs at locations where atomic hydrogen is able to diffuse at sites of high internal stress, such as grain boundaries, inclusions and regions of triaxial stress at notches. The electrochemical and sulfide stress corrosion cracking sscc behaviors of cr stainless steel and p110 steel were investigated in a simulated acidic annular environment with lowtemperature and highpressure h2sco2 using electrochemical methods, ubend immersion tests, and scanning electron microscopy. Sulfide stress cracking ssc also known as sour gas cracking sour gas. However, the crack, pit initiation and growth or any damage may. This is an embrittlement that is caused by liquid metals. Hydrogen induced cracking of subsea duplex stainless steel twi. In the solution containing high pressure co2, cr, and p110 steels. The muscles of the rotator cuff are put under large amounts of stress and are quite prone to tearing. Standard material requirements sulfide stress cracking resistant metallic materials for oilfield equipment contents 1. Large manganese sulphides were found in metallographic specimens not initiating any cracks. Typical damage types of he are hydrogen induced cracking hic and sulfide stress cracking ssc. Sulfide stress cracking is the cracking of a metal under the combined action. Hydrogen embrittlement he also known as hydrogen assisted cracking hac and hydrogeninduced cracking hic, describes the embrittling of metal after being exposed to hydrogen. Damage due to hydrogen embrittlement and stress corrosion.
Once torn, the uneven surfaces can rub together, causing cracking noises. Low alloy steels, stress corrosion cracking, sulfide stress cracking tagged with. The impact of scc on a material usually falls between dry cracking and the fatigue threshold of that material. Mic is not limited to metals and can also affect nonmetallic materials. This phenomenon is generally termed sulfide stress cracking ssc when operating at room temperature and stress corrosion cracking scc when operating at higher temperatures. The results showed that the resistance to sscc of this joint improved first then decline after 98h aging treatments.
Aug 14, 20 variation and degradation of p110 casing steel mechanical properties, due to sulfide stress cracking ssc in sour environments, was investigated using tensile and impact tests. Sulfide, sulfide intrusion, sulfide stress cracking, sulfidecytochromec reductase flavocytochrome c, sulfite reductase, sulfite reductase ferredoxin. The blistering damage tends to form parallel to the surface and to the direction of hoop stress. Ian sutton, in plant design and operations second edition, 2017. The variation of the name is due to the lack of agreement in the mechanism of failure.
Recent experience has demonstrated the risk of sscc and hic, sometimes known as hydrogen embrittlement he, of low strength steels subject to high residual stress derived from fabrication techniques. Eddy current and microtomography to obtain 3d rendition of internal damage. Sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. Hydrogen is generated when steel is exposed to this mixture and.
Sulphide stress cracking ssc is the biggest concern 9. The list of acronyms and abbreviations related to ssc sulfide stress cracking. When placed in proximity to tensile stresses, embrittlement and the beginnings of brittle fracture may occur. Hydrogen sulfide is known to cause or assist in the mechanism of cracking with many alloy types including low carbon steels, low alloy steels, alloy steels, tool steels. Wet hydrogen sulfide refers to any fluid containing water and hydrogen sulfide h 2 s. Sulfide stress cracking of pipelinecase history onepetro. Dec 21, 2017 in other words, it can support a stress of 80,000 psi with an elongation of less than 0. Cras are particularly prone to damage by acidizing chemicals. H2s can cause sulfide stress cracking of stainless steels.
The presence or absence of chlorides, cyanides, or hydrogen sulfide may also be factors but their full role in the cracking mechanism is not completely known at present. Reliability of dissimilar metal welds subjected to sulfide. Electrochemical test was conducted at 23 c and atmospheric pressure. Sulfide stress cracking ssc of high strength, low alloy steel is a phenomenon of particular concern to the oil and gas industry 3. Failure in pipe gw1 occurred at the weld toe and propagated through the haz figure 4 into the parent material. Sulfide stress cracking ssc resistance of casing steels with different alloying chemistries i. It can occur when carbonsteel equipment becomes exposed to wet h 2 s service environments, and it can come in several different forms. Sulfide stress cracking is also called hydrogen sulfide cracking, sulfide cracking, sulfide corrosion cracking and sulfide stresscorrosion cracking. These tests were carried out on specimens, which were pretreated under the following conditions for 168 hours. Hydrogen is generated when steel is exposed to this mixture and the hydrogen can enter into the steel. This is a complex topic, other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking. Sulfide stress crackingnace mr01752002, mr0175iso 15156 651 te c h n i c a l new sulfide stress cracking standard for refineries don bush, principal engineer materials, at emerson process management fisher valves, is a member and former chair of a nace task group that has written a document for refinery applications, nace mr0103. Laboratory testing of metals for resistance to sulfide stress.
Sulfide stress cracking ssc definition sulfide stress cracking ssc is a type of hydrogen cracking which presents a cathodic embrittlement mechanism. Notch tensile slow strain rate testing ntssrt method is used to evaluate the threshold stress intensity values kisscc. It addresses hydrogeninduced cracking of steel weldments, sensitization and subsequent intergranular corrosion of stainless steel weldments, sulfide stress cracking of pipeline steel weldments, microbiologically induced corrosion of weldments, and stresscorrosion cracking of weldments. Effect of carbon migration on sulfide stress corrosion. This term should not be confused with stress corrosion cracking scs, since this is anodic in nature. Sulfide stress cracking nace mr01752002, mr0175iso 15156 651 te c h n i c a l new sulfide stress cracking standard for refineries don bush, principal engineer materials, at emerson process management fisher valves, is a member and former chair of a nace task group that has written a document for refinery applications, nace mr0103. At room temperature, the ssc failure mechanism is believed to be a form of.
Susceptibility to sohic for linepipepressure vessel. Tib and mncrmo was evaluated using constant load tensile test. For this reason, along with toxicity risks of hydrogen sulfide gas, it is essential that water muds be kept entirely free of soluble sulfides and especially hydrogen sulfide at low ph. The embrittlement induced by ssc causes failure of steel at a stress level, which is significantly lower than its yield strength. Wet hydrogen sulfide h2s cracking inspectioneering. In this paper, mechanical performance test, slow strain rate test ssrt and optical microscopy analysis were employed in studying the effect of carbon migration on sulfide stress corrosion cracking sscc behaviors of cr5moa3020cr18ni9 dissimilar joints. The stress corrosion cracking behaviour of uns n08031 in. Susceptible alloys, especially steels, react with hydrogen sulfide, forming metal sulfides and atomic hydrogen as corrosion byproducts. This is the embrittlement caused by the absorption of hydrogen sulfide.
Tib and mncrmo was evaluated using constant load tensile test and slow strain rate test in nacetm0177 environment. Stress corrosion cracking scc is the cracking induced from the combined influence of tensile stress and a corrosive environment. Mechanism of stress corrosion cracking of steels in h 2 s. Used sem observed the fracture, and then the steels corrosion rate and shortterm corrosion behavior were analyzed by electrochemical polarization. This phenomenon is generally termed sulfide stress cracking ssc 1 when operating at room temperature and stress corrosion cracking scc1 when operating at higher temperatures.
H 2 s can cause corrosion of stainless steels such as 316 and 410 stainless in the form of sulfide stress cracking. As we know that both form of cracking are due to the absorption of atomic hydrogen that is produced by. Hydrogen sulfide stress corrosion cracking in materials for. Cracking occurred after less than 12 hours at a strain level of 0. They can tear partially or entirely as a result of age or general wear and tear. Hydrogen induced cracking of low strength steels in. Variation and degradation of p110 casing steel mechanical properties, due to sulfide stress cracking ssc in sour environments, was investigated using tensile and impact tests. Stress corrosion cracking scc is the simultaneous action of a tensile stress and an aggressive environment on an alloy system to produce a brittle fracture in a normally ductile material at stress levels far below engineering design limits. Sulfide stress cracking ssc vs hydrogen induced cracking. The effects of sulfide stress cracking on the mechanical properties. Hic usually occurs due to the effects of aqueous hydrogen charging of steel in wet h2s refinery process.
It is a complex process that is not completely understood because of the variety and complexity of mechanisms that can lead to embrittlement. Wet h2s corrosion can be a particularly dangerous form of corrosion because damage caused by it takes place on the interior of vessels, it can occur without. H 2 s can cause sulfide stress cracking of stainless steels. It addresses hydrogeninduced cracking of steel weldments, sensitization and subsequent intergranular corrosion of stainless steel weldments, sulfide stress cracking of pipeline steel weldments, microbiologically induced corrosion of weldments, and stress corrosion cracking of weldments. Sulfide stress cracking ssc has been the subject of investigation since the. The steels sscc susceptibility was determined by constant load tensile according to nace tm0177 standard. Hydrogen sulfide is the chemical compound with the chemical formula h2s. The authors conducted extensive analyses to explore the effects of metallurgical factors on the resistance of line pipe steels to hydrogen induced cracking hic and sulfide stress cracking ssc. Mic may appear as localised corrosion such as pitting corrosion of vessels or pipelines, particularly in the oil and gas industry. An industry value that has been developed is nace mr01. Apart from sscc, h2s also cause other cracking, including stress corrosion cracking, hydrogeninduced cracking and stepwise cracking, stressoriented hydrogen induced cracking, soft zone cracking and galvanically induced hydrogen stress cracking. To check its resistance to scc and ssc, several tests were performed. Hydrogen induced cracking hic is a common form of wet h2s cracking caused by the blistering of a metal due to a high concentration of hydrogen. Reliability of dissimilar metal welds subjected to sulfide stress cracking vol.
Wet hydrogen sulfide wet hydrogen sulfide refers to any fluid containing water and hydrogen sulfide h2s. Sulfide stress cracking ssc is a form of hydrogen embrittlement which is a cathodic cracking mechanism. Sulfide stress cracking how is sulfide stress cracking. Other factors, such as ph, chloride concentration, and temperature also affect the potential for steel cracking. Laboratory testing of metals for resistance to sulfide.
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